Supported TiO2 photocatalyst synthesis and some applications to water purification
dc.contributor.advisor | Langford, Cooper H. | |
dc.contributor.advisor | Kantzas, Apostolos | |
dc.contributor.author | Chang, Yanjun | |
dc.date.accessioned | 2005-08-16T16:52:50Z | |
dc.date.available | 2005-08-16T16:52:50Z | |
dc.date.issued | 2004 | |
dc.description | Bibliography: p. 162-170 | en |
dc.description.abstract | ZSM-5 supported TiO2 photocatalysts were synthesized by P25 TiO2 and sol gel TiO2 methods, tested by photocatalytic degradation of acetophenone in aqueous media, and characterized by XRD. Degradation results demonstrated higher photoactivities of the photocatalysts prepared by P25 method. Thus, these photocatalysts were intensively studied for better understanding the supported TiO2 photocatalyst. TiO2 maximum coverage on ZSM-5 surface was estimated by solid 1H-29Si CP-MAS FT-NMR to be 23% at 2.5 wt% TiO2 loading, which agree well with literature values. Acetophenone isotherm adsorption result reveals a monolayer and a multi-layer adsorptions and the Langmuir isotherm fits well the monolayer region. A maximum monolayer adsorption of 69.0 mg/g photocatalyst was obtained from Langmuir fitting. Based on the acetophenone molecule dimensions, the maximum acetophenone monolayer adsorption, maximum TiO2 coverage, and ZSM-5 zeolite characteristics, a surface model of TiO2/ZSM-5 is developed quantitatively. | en |
dc.format.extent | xix, 171 leaves : ill. ; 30 cm. | en |
dc.identifier.citation | Chang, Y. (2004). Supported TiO2 photocatalyst synthesis and some applications to water purification (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/14762 | en_US |
dc.identifier.doi | http://dx.doi.org/10.11575/PRISM/14762 | |
dc.identifier.isbn | 0612976351 | en |
dc.identifier.lcc | AC1 .T484 2004 C429 | en |
dc.identifier.uri | http://hdl.handle.net/1880/41396 | |
dc.language.iso | eng | |
dc.publisher.institution | University of Calgary | en |
dc.publisher.place | Calgary | en |
dc.rights | University of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission. | |
dc.title | Supported TiO2 photocatalyst synthesis and some applications to water purification | |
dc.type | master thesis | |
thesis.degree.discipline | Chemistry | |
thesis.degree.grantor | University of Calgary | |
thesis.degree.name | Master of Science (MSc) | |
ucalgary.item.requestcopy | true | |
ucalgary.thesis.accession | Theses Collection 58.002:Box 1493 520492010 | |
ucalgary.thesis.notes | UARC | en |
ucalgary.thesis.uarcrelease | y | en |
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