Supported TiO2 photocatalyst synthesis and some applications to water purification

dc.contributor.advisorLangford, Cooper H.
dc.contributor.advisorKantzas, Apostolos
dc.contributor.authorChang, Yanjun
dc.date.accessioned2005-08-16T16:52:50Z
dc.date.available2005-08-16T16:52:50Z
dc.date.issued2004
dc.descriptionBibliography: p. 162-170en
dc.description.abstractZSM-5 supported TiO2 photocatalysts were synthesized by P25 TiO2 and sol gel TiO2 methods, tested by photocatalytic degradation of acetophenone in aqueous media, and characterized by XRD. Degradation results demonstrated higher photoactivities of the photocatalysts prepared by P25 method. Thus, these photocatalysts were intensively studied for better understanding the supported TiO2 photocatalyst. TiO2 maximum coverage on ZSM-5 surface was estimated by solid 1H-29Si CP-MAS FT-NMR to be 23% at 2.5 wt% TiO2 loading, which agree well with literature values. Acetophenone isotherm adsorption result reveals a monolayer and a multi-layer adsorptions and the Langmuir isotherm fits well the monolayer region. A maximum monolayer adsorption of 69.0 mg/g photocatalyst was obtained from Langmuir fitting. Based on the acetophenone molecule dimensions, the maximum acetophenone monolayer adsorption, maximum TiO2 coverage, and ZSM-5 zeolite characteristics, a surface model of TiO2/ZSM-5 is developed quantitatively.en
dc.format.extentxix, 171 leaves : ill. ; 30 cm.en
dc.identifier.citationChang, Y. (2004). Supported TiO2 photocatalyst synthesis and some applications to water purification (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/14762en_US
dc.identifier.doihttp://dx.doi.org/10.11575/PRISM/14762
dc.identifier.isbn0612976351en
dc.identifier.lccAC1 .T484 2004 C429en
dc.identifier.urihttp://hdl.handle.net/1880/41396
dc.language.isoeng
dc.publisher.institutionUniversity of Calgaryen
dc.publisher.placeCalgaryen
dc.rightsUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.titleSupported TiO2 photocatalyst synthesis and some applications to water purification
dc.typemaster thesis
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Calgary
thesis.degree.nameMaster of Science (MSc)
ucalgary.item.requestcopytrue
ucalgary.thesis.accessionTheses Collection 58.002:Box 1493 520492010
ucalgary.thesis.notesUARCen
ucalgary.thesis.uarcreleaseyen
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