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Title: Activation of Si-H bonds across the nickel carbene bond in electron rich nickel PCcarbeneP pincer complexes
Authors: Piers, Warren E.
LaPierre, Etienne A.
Spasyuk, Denis M.
Bi, David W.
Issue Date: 27-Nov-2015
Publisher: Royal Society of Chemistry
Citation: Chem. Commun., 2016, 52, 1361
Abstract: Silicon–hydrogen bonds are shown to add to a nickel carbon double bond to yield nickel α-silylalkyl hydrido complexes. Kinetic and isotope labeling studies suggest that a concerted 4-centred addition across the Ni[double bond, length as m-dash]C bond is operative rather than a mechanism involving Si–H oxidative addition. This constitutes an example of Si–H bond activation via ligand cooperativity.
Description: Accepted version of article deposited April 11, 2016 as per
Appears in Collections:Piers, Warren E.

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