Bondu, RaphaëlKloppmann, WolframNaumenko-Dèzes, Maria OHumez, PaulineMayer, Bernhard2023-03-182023-03-182021-07-20Bondu, R., Kloppmann, W., Naumenko-Dèzes, M. O., Humez, P., & Mayer, B. (2021). Potential Impacts of Shale Gas Development on Inorganic Groundwater Chemistry: Implications for Environmental Baseline Assessment in Shallow Aquifers. Environmental Science & Technology, 55(14), 9657–9671. https://doi.org/10.1021/acs.est.1c01172http://hdl.handle.net/1880/11593510.11575/PRISM/46117The potential contamination of shallow groundwater with inorganic constituents is a major environmental concern associated with shale gas extraction through hydraulic fracturing. However, the impact of shale gas development on groundwater quality is a highly controversial issue. The only way to reliably assess whether groundwater quality has been impacted by shale gas development is to collect pre-development baseline data against which subsequent changes in groundwater quality can be compared. The objective of this paper is to provide a conceptual and methodological framework for establishing a baseline of inorganic groundwater quality in shale gas areas, which is becoming standard practice as a prerequisite for evaluating shale gas development impacts on shallow aquifers. For this purpose, this paper first reviews the potential sources of inorganic contaminants in shallow groundwater from shale gas areas. Then, it reviews the previous baseline studies of groundwater geochemistry in shale gas areas, showing that a comprehensive baseline assessment includes documenting the natural sources of salinity, potential geogenic contamination, and potential anthropogenic influences from legacy contamination and surface land use activities that are not related to shale gas development. Based on this knowledge, best practices are identified in terms of baseline sampling, selection of inorganic baseline parameters, and definition of threshold levels.engUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.Potential Impacts of Shale Gas Development on Inorganic Groundwater Chemistry: Implications for Environmental Baseline Assessment in Shallow Aquifersjournal articlehttp://dx.doi.org/10.1021/acs.est.1c01172