Song, HuaLuan, Yingqi2016-09-132016-09-1320162016Luan, Y. (2016). Catalytic Bitumen Partial Upgrading using Methane (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/25224http://hdl.handle.net/11023/3289It is highly desired to partially upgrade viscous heavy oil, to be transportable by pipeline. Conventionally, this is achieved by expensive catalytic hydrogenation under a hydrogen pressure of 15–20 MPa. In this thesis, it is reported that by using zinc and silver cation-modified HZSM-5 as the catalyst, methane can be activated at a relatively low temperature of 380 °C and a pressure of 5 MPa to efficiently upgrade heavy oil. The product is a partially upgraded crude oil which is more desirable for pipeline transportation and downstream refining. Before the evaluation of different catalysts, the reaction conditions optimization and better support identification is carried out. The catalyst with the best upgrading performance among all developed candidates comparison was 1 wt% Ag–10 wt% Zn/HZSM-5. This study opens a door for upgrading heavy oil with natural gas.engUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.Engineering--ChemicalEngineering--Petroleumcatalytic bitumen upgradingmaster thesis10.11575/PRISM/25224