Characteristics of a Novel Alkali Flame Ionization Detector as an Air Sensor for Volatile Organonitrogen Compounds

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dc.contributor.advisorThurbide, Kevin
dc.contributor.authorMogenson, Cole Mitchell
dc.contributor.committeememberKimura-Hara, Susana
dc.contributor.committeememberAnikovskiy, Max
dc.contributor.committeememberThangadurai, Venkataraman
dc.date2023-11
dc.date.accessioned2023-05-19T15:15:19Z
dc.date.available2023-05-19T15:15:19Z
dc.date.issued2023-05-05
dc.description.abstractThis thesis describes the introduction and characterization of a novel alkali flame ionization detector (AFID) for use as an air sensor for organonitrogen compounds without any chromatographic separation. Using a planar channelled quartz design, a simple, lightweight architecture for the portable device is presented, which yields a sensitive and selective response toward nitrogen-containing analytes over hydrocarbons. For instance, the AFID sensor offers a detection limit of 30 pg N/s and a selectivity for nitrogen response over carbon of nearly two orders of magnitude. Further, the nitrogen response was linear over the 1000-fold range of concentrations investigated. Relative to a flame photometric detector (FPD) device also used in a sensor mode under optimal conditions, the AFID was observed to provide over a 160 times greater S/N value for nitrogen analytes with a selectivity of nitrogen over carbon that was about 16.6 times larger. When using the AFID and FPD sensors in tandem, it was found that the response ratio of the simultaneous signals generated by each produced characteristic signal ratio values that more clearly identified the presence or absence of nitrogen in unknown analytes. The AFID sensor was also used to detect organonitrogen analytes in several sample matrices. Results indicate that signal response was largely unaffected by these potentially interfering sample conditions, and thus this method could be a valuable approach for portable air sensing of nitrogen compounds.
dc.identifier.citationMogenson, C. M. (2023). Characteristics of a novel alkali flame ionization detector as an air sensor for volatile organonitrogen compounds (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca.
dc.identifier.urihttps://hdl.handle.net/1880/116552
dc.identifier.urihttps://dx.doi.org/10.11575/PRISM/dspace/41395
dc.language.isoen
dc.publisher.facultyGraduate Studies
dc.publisher.institutionUniversity of Calgary
dc.rightsUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.subject.classificationChemistry--Analytical
dc.titleCharacteristics of a Novel Alkali Flame Ionization Detector as an Air Sensor for Volatile Organonitrogen Compounds
dc.typemaster thesis
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Calgary
thesis.degree.nameMaster of Science (MSc)
ucalgary.thesis.accesssetbystudentI do not require a thesis withhold – my thesis will have open access and can be viewed and downloaded publicly as soon as possible.
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