Synthetic Strategies Towards Pi-Extended Dithienophospholes Available for Click Chemistry

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dc.contributor.advisorBaumgartner, Thomas
dc.contributor.advisorWelch, Gregory
dc.contributor.authorMacLean, Liisa
dc.contributor.committeememberSutherland, Todd
dc.contributor.committeememberLing, Chang-Chun
dc.date2018-06
dc.date.accessioned2018-04-26T21:59:43Z
dc.date.available2018-04-26T21:59:43Z
dc.date.issued2018-04-24
dc.description.abstractA series of highly luminescent P-acetylenyl functionalized dithieno[3,2-b:2’,3’-d]phospholes were attempted to be synthesized following the previously studied P-phenyl phosphole as a guide. The original synthesis pathway of forming the dithienophosphole scaffold first, then cross-coupling onto the 2,6-positions, then modifying the acetylene to be able to perform click chemistry saw many difficulties. An alternative route was explored where the cross-coupling reaction with a brominated bithiophene was performed first, then a ring closure reaction to form the phosphole was done. Finally, the emissive materials were able to be clicked onto benzyl azide as a proof-of-concept for an organic light-emitting polymer material for the potential application of solid-state lighting.en_US
dc.identifier.citationMacLean, L. A. (2018). Synthetic Strategies Towards Pi-Extended Dithienophospholes Available for Click Chemistry (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/31839en_US
dc.identifier.doihttp://dx.doi.org/10.11575/PRISM/31839
dc.identifier.urihttp://hdl.handle.net/1880/106553
dc.language.isoeng
dc.publisher.facultyGraduate Studies
dc.publisher.facultyScience
dc.publisher.institutionUniversity of Calgaryen
dc.publisher.placeCalgaryen
dc.rightsUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.subject.classificationEducation--Sciencesen_US
dc.subject.classificationChemistry--Organicen_US
dc.subject.classificationEngineering--Chemicalen_US
dc.titleSynthetic Strategies Towards Pi-Extended Dithienophospholes Available for Click Chemistry
dc.typemaster thesis
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Calgary
thesis.degree.nameMaster of Science (MSc)
ucalgary.item.requestcopytrue
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