A vinylogous Norrish reaction as a strategy for light-mediated ring expansion

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dc.contributor.authorEvgueni Gorobets
dc.contributor.authorJames W. Papatzimas
dc.contributor.authorJorge Dourado
dc.contributor.authorGoonay Yousefalizadeh
dc.contributor.authorJinGyu Lee
dc.contributor.authorDuncan K. Brownsey
dc.contributor.authorKevin Stamplecoskie
dc.contributor.authorRebecca Davis
dc.contributor.authorDarren J. Derksen
dc.date.accessioned2024-04-10T21:37:54Z
dc.date.available2024-04-10T21:37:54Z
dc.date.issued2022-02-03
dc.description.abstractThe reactions of bicyclic divinyl ketones display wavelength-dependent changes in product formation. UV irradiation results in the formation of competitive and tricyclic unsaturated ketones that subsequently undergo ring expansion and reaction with a range of nucleophiles. DFT calculations and transient absorption experiments were completed that are consistent with a vinylogous Type II Norrish pathway.
dc.description.grantingagencyNatural Sciences and Engineering Research Council (NSERC)
dc.identifier.citationA vinylogous Norrish reaction as a strategy for light-mediated ring expansion—Chemical Communications (RSC Publishing). (n.d.). Retrieved April 10, 2024, from https://pubs.rsc.org/en/content/articlelanding/2022/cc/d2cc00513a
dc.identifier.doihttps://doi.org/10.1039/D2CC00513A
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttps://hdl.handle.net/1880/118363
dc.identifier.urihttps://doi.org/10.11575/PRISM/43205
dc.language.isoenen
dc.publisherRoyal Society of Chemistry
dc.publisher.facultyScienceen
dc.publisher.hasversionacceptedVersion
dc.publisher.institutionUniversity of Calgaryen
dc.publisher.policyhttps://www.rsc.org/journals-books-databases/open-access-publishing/
dc.relation.ispartofChemical Communications
dc.rightsUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.en
dc.titleA vinylogous Norrish reaction as a strategy for light-mediated ring expansion
dc.typeArticle
oaire.citation.issue17
oaire.citation.volume58
ucalgary.scholar.levelFaculty
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