Emerging disinfection by-product quantification method for wastewater reuse: trace level assessment using tandem mass spectrometry

dc.contributor.authorOrtega-Hernandez, Alejandro
dc.contributor.authorAcabaya, Raphael
dc.contributor.authorVerwold, Chad
dc.contributor.authorMontagner, Cassiana Carolina
dc.contributor.authorKimura, Susana Y.
dc.date.accessioned2023-02-03T23:25:00Z
dc.date.available2023-02-03T23:25:00Z
dc.date.issued2021-01-13
dc.description.abstractThe availability of freshwater sources are declining as the result of increasing populations, economic activities, and climate change. These increasing trends will also drive up the demand for potable water that will require the use of alternative sources including wastewater-impacted and saline waters. Therefore, it is crucial to understand the formation of emerging toxic DBPs from advanced treatment of treated secondary wastewater effluents for potable reuse. In this study, a highly sensitive analytical method was developed to characterize 25 DBPs from 5 chemical classes (haloacetonitriles, halonitromethanes, haloacetaldehydes, haloketones, and iodinated trihalomethanes) in recycled wastewaters using a gas chromatography tandem mass spectrometer (MS/MS). The high sensitivity of MS/MS technology permitted a reduced sample concentration factor (50x) that required only 30 min of extraction time and 10 mL of sample volume. Method detection limits are the lowest reported between 2.0-68.9 ng/L. Matrix effects in secondary wastewater effluents were low (0-30%) compared to ultra pure water. A full-scale facility for wastewater reuse that treated secondary wastewater effluents through microfiltration (UF), followed by ozone (UF/O3) or reverse osmosis (UF/RO) was evaluated. Water samples from each process were chlorinated (HOCl) and chloraminated (NH2Cl) to evaluate DBP precursor removal and DBP formation potential, the first study of its kind. Overall, HOCl formed higher summed DBP levels (0.5-18.5 ug/L) compared to NH2Cl (0.2-8.5 ug/L). HAN was significantly lower in UF/O3/HOCl (59%) and UF/RO/HOCl (99%) compared to UF/HOCl. However, HNM was enhanced after UF/O3/HOCl. In chloraminated samples, UF/O3/NH2Cl produced a higher amount of DBPs compared to UF/NH2Cl including haloacetonitriles, halonitromethanes, haloketones, and iodinated trihalomethanes.en_US
dc.description.grantingagencyNatural Sciences and Engineering Research Council (NSERC)en_US
dc.identifier.citationOrtega-Hernandez, A., Acayaba, R., Verwold, C., Montagner, C. C., & Kimura, S. Y. (2021). Emerging investigator series: Emerging disinfection by-product quantification method for wastewater reuse: trace level assessment using tandem mass spectrometry. Environmental Science: Water Research & Technology, 7(2), 285–297. https://doi.org/10.1039/D0EW00947Den_US
dc.identifier.doihttps://doi.org/10.1039/D0EW00947Den_US
dc.identifier.urihttp://hdl.handle.net/1880/115808
dc.identifier.urihttps://doi.org/10.11575/PRISM/46085
dc.language.isoengen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentChemistryen_US
dc.publisher.facultyScienceen_US
dc.publisher.hasversionacceptedVersionen_US
dc.publisher.policyhttps://www.rsc.org/journals-books-databases/open-access-publishing/how-to-publish-open-access/#more-optionsen_US
dc.rightsUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.en_US
dc.subjectDBPsen_US
dc.titleEmerging disinfection by-product quantification method for wastewater reuse: trace level assessment using tandem mass spectrometryen_US
ucalgary.item.requestcopytrueen_US
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