Self-Assembly and Unique Phosphorus Chemistry of Dithienophospholes

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atmire.migration.oldid5760
dc.contributor.advisorBaumgartner, Thomas
dc.contributor.authorWang, Zisu
dc.contributor.committeememberSutherland, Todd
dc.contributor.committeememberHeyne, Belinda
dc.contributor.committeememberMuench, Douglas
dc.contributor.committeememberTykwinski, Rik
dc.date.accessioned2017-07-10T16:44:33Z
dc.date.available2017-07-10T16:44:33Z
dc.date.issued2017
dc.date.submitted2017en
dc.description.abstractIn this thesis, first, the self-assembly features of the dithienophosphole system were explored by controlling the structural features of the compounds. By varying different directing forces and tuning their strength, a wide variety of self-assembly motifs with interesting optoelectronic features was achieved. Second, the unique chemistry involving the exocyclic R substituent at the phosphorus centre of the phosphole was discussed. Direct functionalization of the phosphole post ring closing can be achieved conveniently through newly synthesized chlorophosphole precursors. Furthermore, an unprecedented method for the construction of P-P single bond was discussed in mechanistic detail.en_US
dc.identifier.citationWang, Z. (2017). Self-Assembly and Unique Phosphorus Chemistry of Dithienophospholes (Doctoral thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/27745en_US
dc.identifier.doihttp://dx.doi.org/10.11575/PRISM/27745
dc.identifier.urihttp://hdl.handle.net/11023/3933
dc.language.isoeng
dc.publisher.facultyGraduate Studies
dc.publisher.institutionUniversity of Calgaryen
dc.publisher.placeCalgaryen
dc.rightsUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.subjectChemistry--Inorganic
dc.subject.otherphosphole
dc.subject.othermaterial
dc.subject.otherself-assembly
dc.subject.otherphosphorus chemistry
dc.titleSelf-Assembly and Unique Phosphorus Chemistry of Dithienophospholes
dc.typedoctoral thesis
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Calgary
thesis.degree.nameDoctor of Philosophy (PhD)
ucalgary.item.requestcopytrue
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