Photo Lewis Acid Generators: Photorelease of B(C6F5)3 and Applications to Catalysis.

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dc.contributor.authorPiers, Warren E.
dc.contributor.authorKhalimon, Andrey Y.
dc.contributor.authorMarwitz, Adam A. J.
dc.contributor.authorShaw, Bryan K.
dc.contributor.authorParvez, Masood
dc.contributor.authorBlackwell, James M.
dc.date.accessioned2016-04-13T07:48:11Z
dc.date.available2016-04-13T07:48:11Z
dc.date.issued2015-09-24
dc.descriptionAccepted manuscript deposited April 11, 2016, as per http://www.rsc.org/journals-books-databases/journal-authors-reviewers/licences-copyright-permissions/#deposition-sharingen_US
dc.description.abstractA series of molecules capable of releasing of the strong organometallic Lewis acid B(C6F5)3 upon exposure to 254 nm light have been developed. These photo Lewis acid generators (PhLAGs) can now serve as photoinitiators for several important B(C6F5)3-catalyzed reactions. Herein is described the synthesis of the triphenylsulfonium and diphenyliodonium salts of carbamato- and hydridoborates, their establishment as PhLAGs, and studies aimed at defining the mechanism of borane release. Factors affecting these photolytic reactions and the application of this concept to photoinduced hydrosilylation reactions and construction of siloxane scaffolds are also discussed.en_US
dc.description.grantingagencyNSERCen_US
dc.description.refereedYesen_US
dc.identifier.citationDalton Trans., 2015, 44, 18196en_US
dc.identifier.doi10.1039/c5dt03008k
dc.identifier.doihttp://dx.doi.org/10.11575/PRISM/35409
dc.identifier.urihttp://hdl.handle.net/1880/51144
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.publisher.departmentChemistryen_US
dc.publisher.facultyScienceen_US
dc.publisher.institutionUniversity of Calgaryen_US
dc.publisher.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT03008K#!divAbstracten_US
dc.titlePhoto Lewis Acid Generators: Photorelease of B(C6F5)3 and Applications to Catalysis.en_US
dc.typejournal article
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