Oil Sand Remediation

dc.contributor.advisorGates, Ian
dc.contributor.authorMislan, Michael
dc.contributor.committeememberDe la Hoz Siegler, Hector
dc.contributor.committeememberPonnurangam, Sathish
dc.contributor.committeememberHu, Jinguang
dc.contributor.committeememberGieg, Lisa
dc.contributor.committeememberJin, Zhehui
dc.date2021-11
dc.date.accessioned2021-10-06T22:26:07Z
dc.date.available2021-10-06T22:26:07Z
dc.date.issued2021-09
dc.description.abstractOil sand has become an important part of the Canadian economy. It is also a natural, toxic substance. Bitumen and clay suspensions are discussed in context of their position in the biogeochemical carbon and rock cycles, respectively. In the first section, bitumen is described as a product of soil organic matter matured over geological history affected by microbial and environmental conditions. Biological moieties have been preserved intact inside asphaltene-maltene complexes due to the fact that bitumen is fossilized soil or sedimentary organic matter. Therefore the biodegradation of bitumen by common soil biodegrading enzymes is demonstrated using Lipase, for lipid fats, and Cellulase, which degrades the most abundant photosynthetically produced polysaccharide biomass on earth cellulose. These enzymes are able to hydrolytically release biomolecular fragments from bitumen, refluxing them back into the biosphere and carbon cycle. In the second section, similarly to how sedimentary minerals metamorphosize naturally, mature fine tailings (MFT) is geopolymerized to produce a metamorphic, hydrated zeolite solid. MFT samples in tanks were mixed with 1 kg KOH 1 kg K2SiO3/m3 Raw MFT and shown to solidify after 20 days, demonstrating better performance than many competing remediation techniques. In general it is demonstrated that naturalistic methods for oil sand remediation may be possible because oil sand is a natural geological product of aquatic ecosystems.en_US
dc.identifier.citationMislan, M. (2021). Oil sand remediation (Doctoral thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca.en_US
dc.identifier.doihttp://dx.doi.org/10.11575/PRISM/39341
dc.identifier.urihttp://hdl.handle.net/1880/114034
dc.language.isoengen_US
dc.publisher.facultySchulich School of Engineeringen_US
dc.publisher.institutionUniversity of Calgaryen
dc.rightsUniversity of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.en_US
dc.subjectBitumenen_US
dc.subject.classificationBiogeochemistryen_US
dc.titleOil Sand Remediationen_US
dc.typedoctoral thesisen_US
thesis.degree.disciplineEngineering – Chemical & Petroleumen_US
thesis.degree.grantorUniversity of Calgaryen_US
thesis.degree.nameDoctor of Philosophy (PhD)en_US
ucalgary.item.requestcopytrueen_US
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