Prediction of complex phase behaviour
| dc.contributor.advisor | Moore, R. Gordon | |
| dc.contributor.author | Evelein, Katherine A. | |
| dc.date.accessioned | 2005-07-19T22:19:43Z | |
| dc.date.available | 2005-07-19T22:19:43Z | |
| dc.date.issued | 1976 | |
| dc.description | Bibliography: p. 212-220. | en |
| dc.description.abstract | A correlation of phase behaviour based on the Redlich-Kwong equation of state is presented. Its success in cal culating phase equilibria is demonstrated for all of the binari es that can be formed from water, hydrogen sulphide , carbon dioxide, nitrogen, methane, ethane, and propaneg Some limited success is demonstrated with binaries involving hydrogen and nitrogen, methane, and ethane. Soave's correlation for the a coefficient, with a small modification for water, is used. Empirical interaction parameters are included in the mixing rules for a and b. The types of complex phase behaviour reproduced by this correlation include three phase equilibrium states, azeotropism, and retrograde phenomena. Predicted and experimental phase behaviour for the three ternaries methane-ethane-propane~ nitrogen-methane-ethane, and nitrogen-carbon dioxide-methane are compared. This demonstrates that the correlation can be extended to multicomponent systems without further modification. | |
| dc.description.notes | This title is not available online. Access options are: - consulting the copy from Archives in our reading room in person - https://asc.ucalgary.ca/visiting/ - borrowing a circulating copy from the Library catalogue – https://ucalgary.primo.exlibrisgroup.com/discovery/search?vid=01UCALG_INST:UCALGARY&lang=en | |
| dc.format.extent | xv, 222 leaves : ill. ; 30 cm. | en |
| dc.identifier | 82480957 | en |
| dc.identifier.citation | Evelein, K. A. (1976). Prediction of complex phase behaviour (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/11329 | en_US |
| dc.identifier.doi | http://dx.doi.org/10.11575/PRISM/11329 | |
| dc.identifier.lcc | TP 156 E65 E86 1976 Microfiche | en |
| dc.identifier.other | 82480957 | en |
| dc.identifier.uri | http://hdl.handle.net/1880/15639 | |
| dc.language.iso | eng | |
| dc.publisher.faculty | Engineering | |
| dc.publisher.institution | University of Calgary | en |
| dc.publisher.place | Calgary | en |
| dc.rights | University of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission. | |
| dc.subject.lcc | TP 156 E65 E86 1976 Microfiche | en |
| dc.subject.lcsh | Phase rule and equilibrium | |
| dc.subject.lcsh | Vapor-liquid equilibrium | |
| dc.subject.lcsh | Chemical equilibrium | |
| dc.title | Prediction of complex phase behaviour | |
| dc.type | master thesis | |
| thesis.degree.discipline | Chemical Engineering | |
| thesis.degree.grantor | University of Calgary | |
| thesis.degree.name | Master of Science (MSc) | |
| ucalgary.thesis.accession | Theses Collection 58.002:Box 257 82480957 | |
| ucalgary.thesis.notes | PL | en |
| ucalgary.thesis.uarcrelease | no | en |