Chemically Stable Proton Conducting Doped BaCeO3 -No More Fear to SOFC Wastes

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dc.contributor.authorKannan, Ramaiyan
dc.contributor.authorSingh, Kalpana
dc.contributor.authorGill, Sukhdeep
dc.contributor.authorFürstenhaupt, Tobias
dc.contributor.authorThangadurai, Venkataraman
dc.date.accessioned2020-02-28T22:22:01Z
dc.date.available2020-02-28T22:22:01Z
dc.date.issued2013-07-04
dc.description.abstractDevelopment of chemically stable proton conductors for solid oxide fuel cells (SOFCs) will solve several issues, including cost associated with expensive inter-connectors and long-term durability. Best known Y-doped BaCeO3 (YBC) proton conductors-based SOFCs suffer from chemical stability under SOFC by-products including CO2 and H2O. Here, for the first time, we report novel perovskite-type Ba0.5Sr0.5Ce0.6Zr0.2Gd0.1Y0.1O3?? by substituting Sr for Ba and co-substituting Gd + Zr for Ce in YBC that showed excellent chemical stability under SOFC by-products (e.g., CO2 and H2O) and retained a high proton conductivity, key properties which were lacking since the discovery of YBCs. In situ and ex- situ powder X-ray diffraction and thermo-gravimetric analysis demonstrate superior structural stability of investigated perovskite under SOFC by-products. The electrical measurements reveal pure proton conductivity, as confirmed by an open circuit potential of 1.15?V for H2-air cell at 700°C and merits as electrolyte for H-SOFCs.
dc.identifier.citationKannan, R., Singh, K., Gill, S., Fürstenhaupt, T., & Thangadurai, V. (2013). Chemically Stable Proton Conducting Doped BaCeO3 -No More Fear to SOFC Wastes. Scientific Reports, 3(1). https://doi.org/10.1038/srep02138
dc.identifier.doi10.1038/srep02138
dc.identifier.issn2045-2322
dc.identifier.urihttp://hdl.handle.net/1880/111699
dc.identifier.urihttps://dx.doi.org/10.11575/PRISM/37618
dc.language.isoenen
dc.language.isoeng
dc.publisherSpringer Science and Business Media LLC
dc.publisher.departmentDepartment of Chemistry
dc.publisher.facultyScienceen
dc.publisher.hasversionpublishedVersion
dc.publisher.institutionUniversity of Calgaryen
dc.rightsUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.en
dc.rightsUnless otherwise indicated, this material is protected by copyright and has been made available with authorization from the copyright owner. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/
dc.subjectCeramics
dc.subjectElectronic materials
dc.subjectFuel cells
dc.subjectSolid-state chemistry
dc.titleChemically Stable Proton Conducting Doped BaCeO3 -No More Fear to SOFC Wastes
dc.typejournal article
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