Activation of Si-H bonds across the nickel carbene bond in electron rich nickel PCcarbeneP pincer complexes

Piers, Warren E.; LaPierre, Etienne A.; Spasyuk, Denis M.; Bi, David W.

Activation of Si-H bonds across the nickel carbene bond in electron rich nickel PCcarbeneP pincer complexes

dc.contributor.author	Piers, Warren E.
dc.contributor.author	LaPierre, Etienne A.
dc.contributor.author	Spasyuk, Denis M.
dc.contributor.author	Bi, David W.
dc.date.accessioned	2016-04-13T07:48:47Z
dc.date.available	2016-04-13T07:48:47Z
dc.date.issued	2015-11-27
dc.description	Accepted version of article deposited April 11, 2016 as per http://www.rsc.org/journals-books-databases/journal-authors-reviewers/licences-copyright-permissions/#deposition-sharing	en_US
dc.description.abstract	Silicon–hydrogen bonds are shown to add to a nickel carbon double bond to yield nickel α-silylalkyl hydrido complexes. Kinetic and isotope labeling studies suggest that a concerted 4-centred addition across the Ni[double bond, length as m-dash]C bond is operative rather than a mechanism involving Si–H oxidative addition. This constitutes an example of Si–H bond activation via ligand cooperativity.	en_US
dc.description.grantingagency	NSERC	en_US
dc.description.refereed	Yes	en_US
dc.identifier.citation	Chem. Commun., 2016, 52, 1361	en_US
dc.identifier.doi	10.1039/c5cc09349j
dc.identifier.doi	http://dx.doi.org/10.11575/PRISM/35407
dc.identifier.uri	http://hdl.handle.net/1880/51146
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.publisher.department	Chemistry	en_US
dc.publisher.faculty	Science	en_US
dc.publisher.institution	University of Calgary	en_US
dc.publisher.url	http://pubs.rsc.org/EN/content/articlelanding/2015/cc/c5cc09349j#!divAbstract	en_US
dc.title	Activation of Si-H bonds across the nickel carbene bond in electron rich nickel PCcarbeneP pincer complexes	en_US
dc.type	journal article