Evaluation of Measurement Techniques for the Adsorption of Asphaltenes onto Metal Oxide Nanoparticles

Ezeonyeka, Nkiru Lucia

Evaluation of Measurement Techniques for the Adsorption of Asphaltenes onto Metal Oxide Nanoparticles

dc.contributor.advisor	Husein, Maen M.
dc.contributor.author	Ezeonyeka, Nkiru Lucia
dc.contributor.committeemember	Yarranton, Harvey William
dc.contributor.committeemember	Hill, Josephine Mary
dc.date	2018-11
dc.date.accessioned	2018-05-30T19:53:05Z
dc.date.available	2018-05-30T19:53:05Z
dc.date.issued	2018-05-22
dc.description.abstract	The adsorption of asphaltenes onto nanoparticles (NPs) has received a lot of attention in the recent years owing to its important application in areas such as heavy oil recovery. The effect of the measurement technique on the adsorption isotherms has never been addressed, however. In this work, the adsorption of n-heptane-precipitated asphaltenes, C7-asphaltenes, from toluene model solutions onto three metal oxide NPs; namely Fe2O3, Fe3O4, and Al2O3, was studied. Most results on asphaltenes adsorption employed UV-Vis spectroscopy, especially when using conventional adsorbents. More recently, and with advent of NPs, thermogravimetric analysis (TGA) has also been used. In this investigation, asphaltenes uptake calculated from UV-Vis spectroscopy at three different wavelengths were compared with thermogravimetric analysis (TGA) results. Although the adsorption trends followed Langmuir isotherms, instrument as well as wavelength-dependent adsorption coefficients were obtained. TGA results are believed to be more reliable, provided complete oxidation and account of mass loss due to NPs is attained. UV-Vis measurements, on the other hand, may be impacted by the chemical structure of the asphaltenes sub fractions as well as their state of association. Al2O3 showed the highest adsorption capacity of 385 ± 5 mg/g, followed by Fe3O4 and Fe2O3. However, based on mg/m2, Fe2O3 displayed the highest adsorption capacity. TGA analysis revealed that the NPs promoted the oxidation of adsorbed asphaltenes in a reverse order to their adsorption capacity, qmax (mg/g) (Al2O3 > Fe2O3 ≈ Fe3O4). This trend is in line with a previous observation of mass-dependent thermo-oxidative profile and surface exposure role, rather than a catalyst role, of the NPs.	en_US
dc.identifier.citation	Ezeonyeka, N. L. (2018). Evaluation of Measurement Techniques for the Adsorption of Asphaltenes onto Metal Oxide Nanoparticles (Master's thesis, University of Calgary, Calgary, Canada). Retrieved from https://prism.ucalgary.ca. doi:10.11575/PRISM/31961	en_US
dc.identifier.doi	http://dx.doi.org/10.11575/PRISM/31961
dc.identifier.uri	http://hdl.handle.net/1880/106716
dc.language.iso	eng
dc.publisher.faculty	Graduate Studies
dc.publisher.faculty	Schulich School of Engineering
dc.publisher.institution	University of Calgary	en
dc.publisher.place	Calgary	en
dc.rights	University of Calgary graduate students retain copyright ownership and moral rights for their thesis. You may use this material in any way that is permitted by the Copyright Act or through licensing that has been assigned to the document. For uses that are not allowable under copyright legislation or licensing, you are required to seek permission.
dc.subject	Asphaltenes
dc.subject	Adsorption
dc.subject	UV-Vis Spectroscopy
dc.subject	Thermogravimetric analysis
dc.subject	XRD
dc.subject	Nanoparticles
dc.subject	TGA
dc.subject.classification	Applied Sciences	en_US
dc.subject.classification	Engineering	en_US
dc.title	Evaluation of Measurement Techniques for the Adsorption of Asphaltenes onto Metal Oxide Nanoparticles
dc.type	master thesis
thesis.degree.discipline	Chemical and Petroleum Engineering
thesis.degree.grantor	University of Calgary
thesis.degree.name	Master of Science (MSc)
ucalgary.item.requestcopy	true